They have the same cup volume.
They're sister sizes.
KINDA.
Because you only ask 32B and 34A in your question initially. These 2 are sister sizes.
But a 30B is in no way the same cup volume as a 36A.
a 32B means 32 inches around the ribs and a B cup
a 32A means 34 inches around the ribs and an A cup
you can fit into both because 32B's band is smaller/the cup is bigger, but the 34A's band is bigger around the ribs.
they aren't the same though
They are close to the same but you can usually feel the slight difference.
They are very similar, especially in terms of actual cup volume. The main difference is that a 32B will fit a smaller ribcage than a 34A. Hope this helps.